Water Quality Monitoring Program
Woods Hole Sea Grant's outreach partners at the Cape Cod Cape Cod Cooperative Extension monitor water quality at four embayments around Cape Cod. These are Wellfleet Harbor, Barnstable Harbor, Pleasant Bay (Orleans), and Cotuit Bay and one on Boston's south shore at Duxbury Bay. These sites have been monitored for a number of years in hopes of capturing any changes or trends in conditions, as well as the typical daily and seasonal trends specific to the body of water. Live data from Wellfleet Harbor and Cotuit Bay are available every 15 minutes via a cellular modem. The archived data are available and specific requests beyond what is available can be made to the marine extension staff.
The water quality conditions are monitored using YSI sondes, which are capable of monitoring multiple parameters with a single device. Measurements of all water quality parameters are recorded by the YSI sondes every 15 minutes and stored internally. This data are then uploaded directly from the sondes to a computer for analysis. The data from Wellfleet Harbor and Cotuit Bay can be viewed in real time.
Due to the nature of the marine environment and the instrument sensors, the sondes are deployed for only 2-4 weeks before they need to be taken in for cleaning and recalibration of sensors. At the time when a sonde is removed from the water for cleaning, recalibration, and data acquisition it is usually replaced with another. To prevent any possibility of ice damage to equipment, data is generally recorded from March/April through November/December.
- Salinity, total dissolved solids (TDS), and conductivity
- Depth, pressure
- Dissolved oxygen
Temperature: Temperature is recorded as it is often one of the most important factors influencing the growth of marine and aquatic organisms. Many other water quality parameters and biological processes may also be influenced by temperature. There is also evidence that certain parasites and other potential pathogens to fish and shellfish vary in abundance according to physical properties like temperature and salinity. The temperature can be recorded in both Fahrenheit (F) or Celsius (C) and converted using the following conversion equations: °F = (1.8 x °C) +32 and °C = (°F-32) x 0.555
Salinity (ppt = parts per thousand): The percentage of salts dissolved in full strength seawater is approximately 3.5% (or 35 ppt) and can vary slightly depending on location, depth and season. Factors that may dilute or lower salt concentrations include precipitation, river or storm water runoff, and ice melt. For instance, a lower level of salinity may occur after the influence of storm water runoff from a nearby storm drain or parking lot. Conversely, the salt concentration may be increased by evaporation or drought. Changes in salinity can stress marine organisms, as well as allow the opportunity for proliferation of different fouling or pathogenic organisms.
Total Dissolved Solids (g/L): Total dissolved solids (TDS) is the amount of dissolved solids in a certain volume of water. This parameter is related to the amount of dissolved salts and minerals in the water.
Conductivity (mS/cm): Conductivity is the measurement of the ability of water to carry an electric current. Conductivity is used to help determine TDS and salinity values. After the specific conductivity reading is obtained, it is used in an equation to calculate salinity and TDS. As conductivity increases so does the salinity and TDS.
Depth (m): The depth is measured in meters (1 meter = 3.28 feet). It is important to know the depth at which the parameters are measured because of factors which may affect the parameter at various depths. There are several reasons to consider the depth when measuring water quality parameters. Examples: water temperature, chlorophyll, and turbidity decrease as the depth increases while salt concentrations generally increase with depth. Small variations in typical measurements could be the result of changing depth depending on the sonde location and placement or recent rainfall events.
Depth can also be used to proxy the height or amplitude of a tide at stations where the sonde is at a fixed level and does not rise and fall with the tide. The YSI sonde stations used by the Cape Cod Cooperative Extension are at fixed level at most sites (Wellfleet Harbor, Pleasant Bay, and Cotuit Bay) and allow for tide measurement. The Barnstable Harbor site moves up and down with the tide and provides a constant measurement of water parameters just below the surface.
pH: In scientific terms pH stands for “potential hydrogen” which is an overall measure for the acid/alkaline balance. The pH level is measured on a scale from 0 to 14 where 0 is the highest acidic concentration and 14 is the most alkaline. The pH of a body of water or solution is determined by the hydrogen ion concentration activity and is expressed mathematically as pH = -log [H]. It is important for pH to remain at a balanced level for marine life as changes can affect physiological processes like the ability to utilize oxygen and quickly induce stress. The average pH of ocean surface water is approximately 8 but varies with environmental circumstances and location. Ocean acidification, or a decrease in pH, has become an increased concern over the past decades as increased atmospheric carbon dioxide is dissolved in the oceans, further warranting the long term observances of pH levels.
DO (or ODO): Dissolved oxygen (DO) is an important parameter to measure because it strongly characterizes the health of a water body as a necessary element for marine life. DO is measured as the amount of gaseous oxygen (O2) dissolved in water, and is measured by the YSI sondes in both percentage saturation (%) and milligrams per liter (mg/L). Algae normally produce oxygen through respiration such that measured surface DO levels are often higher during daylight hours. A low DO level may indicate high levels of decaying algae and/or waste products. Low DO levels could also be the result of warmer water temperatures as the oxygen capacity of water is inversely correlated with water temperature, i.e. as water temperature increases the DO saturation level of the water decreases. Depending on the particular probe used the DO will be expressed as DO or ODO (optical dissolved oxygen).
Chlorophyll (ug/L): Chlorophyll is a pigment that is responsible for photosynthesis in plants. Obtaining a chlorophyll concentration measurement is a way to estimate phytoplankton levels as chlorophyll is directly linked with the amount phytoplankton or algae suspended in the water. Phytoplankton consume available dissolved nutrients and carbon dioxide with the aid of sunlight during photosynthesis, which results in energy for the algae and oxygen which is released to the surrounding water. Understanding phytoplankton populations and their distributions can help understand the health of a water body, as the algae serve as a base food source for the ecosystem, but may also indicate conditions of eutrophication as nutrient levels start to overload the system. Higher levels of algae (chlorophyll concentration) can cloud the waters so that the bottom is shaded, hampering photosynthesis by submerged vegetation and decreasing dissolved oxygen available at the bottom. Also, as algae bloom in eutrophic conditions then settle and decay on the bottom, oxygen is used by bacteria consuming the decaying algae decreasing further the available oxygen.
Turbidity (nephelometric turbidity units or NTUs): This measurement reflects the amount of suspended solids in the water, or the overall clarity or cloudiness. If the water is cloudy it may indicate increases in the amount of suspended particulates. Sometimes the suspended particulates can direct us to potential situations causing change in turbidity readings such as coastal erosion, runoff, waste discharges, and planktonic organisms. Increased levels of turbidity will often impede light transmittance through the water which is of importance to submerged aquatic vegetation like sea grasses, which provide habitat to a number of species.